3-Amino-6-nitroamino-tetrazine (ANAT)-based energetic salts.
نویسندگان
چکیده
The synthesis and properties of several new high-nitrogen materials with 3-amino-6-nitroamino-tetrazine (ANAT) as the anion are reported; all salts were fully characterized by IR and NMR spectroscopy, and elemental analysis.
منابع مشابه
Unimolecular decomposition of tetrazine-N-oxide based high nitrogen content energetic materials from excited electronic states.
Unimolecular excited electronic state decomposition of novel high nitrogen content energetic molecules, such as 3,3(')-azobis(6-amino-1,2,4,5-tetrazine)-mixed N-oxides (DAATO(3.5)), 3-amino-6-chloro-1,2,4,5-tetrazine-2,4-dioxide (ACTO), and 3,6-diamino-1,2,4,5-tetrazine-1,4-dioxde (DATO), is investigated. Although these molecules are based on N-oxides of a tetrazine aromatic heterocyclic ring, ...
متن کاملمروری بر روش‌های سنتز، خواص فیزیکی و انفجاری برخی هتروسیکل‌های پرانرژی با اتصال آزو
In this study, the recent developments in the synthesis of some azo- linked high- nitrogen energetic heterocycles such as tetrazole, triazole, imidazole, pyrazole, triazine, tetrazine and their salts will be investigated. These energetic compounds generally exhibit desirable properties and performance, which in some cases are superior to the conventional energetic materials such as hexahydro-1,...
متن کاملEnergetic Nitrogen-rich Salts
Abstract: Energetic salts as a unique class of energetic materials have recently been investigated widely, since they possess advantages over their atomically similar nonionic analogues – they tend to exhibit lower vapor pressures, higher densities and better thermal stabilities. Furthermore, these salts are readily improved upon by the appropriate combination of different cations and anions. O...
متن کاملThe nitration pattern of energetic 3,6-diamino-1,2,4,5-tetrazine derivatives containing azole functional groups.
One of the successful strategies for the design of promising new energetic materials is the incorporation of both fuel and oxidizer moieties into the same molecule. Therefore, during recent years, synthesis of various nitro-azole derivatives, as compounds with a more balanced oxygen content, has become very popular. In the framework of this effort, we studied nitration of N(3),N(6)-bis(1H-tetra...
متن کاملEnergetic salts based on dipicrylamine and its amino derivative.
Energetic salts based on dipicrylamine and its amino derivative were synthesized. All salts were fully characterized by multinuclear NMR spectroscopy ((1)H, (13)C), vibrational spectroscopy (IR), and elemental analysis. Ethylenediammonium di-DPA (DPA=dipicrylamine) and 1,3-diaminoguanidinium DPA were further confirmed by single-crystal X-ray diffraction. These salts exhibit reasonable physical ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 38 شماره
صفحات -
تاریخ انتشار 2006